The nickel, copper and zinc complexes of a potentially heptadentate nitrogen donor ligands
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چکیده
منابع مشابه
The binding assessment with human serum albumin of novel six-coordinate Pt(IV) complexes, containing bidentate nitrogen donor/methyl ligands
The interactions between platinum complexes and human serum albumin (HSA) play crucial roles in the distribution, metabolism, and activity of platinum-based anticancer drugs. Octahedral platinum (IV) complexes represent a significant class of anticancer agents that display molecular pharmacological properties different from cisplatin. In this study, the interaction between two Pt(IV) complexes ...
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Two potentially heptadentate (N4O3) tripodal Schiff-base ligands: tris(3(salicylideneimino)propyl)amine (H3L1) and tris(3-(4'-hydroxysalicylideneimino)propyl)amine (H3L2) have been prepared and characterized by various spectroscopic methods (IR, FAB-MS, NMR). They are derived from the condensation reactions of tris(3-aminopropyl)amine (tpt), with 3 equivalents of either salicylaldehyde or the r...
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this work is presented in five parts. in the first part preparation of the starting complex [pt(c^n)cl(dmso)], 1, in which c^n = n(1),c(2?)-chelated, deprotonated 2-phenylpyridine, and dmso = dimethylsulfoxide, and its reaction with 1 equiv of the biphosphine ligands bis(diphenylphosphino)amine, dppa, or bis(diphenylphosphino)methane, dppm, to give the complex [pt(c^n)cl(dppa)], 2, or [pt(c^n)c...
15 صفحه اولSpectrophotometric Study of Cobalt, Nickel, Copper, Zinc and Lead Complexes with Methylthymol Blue in Binary Water-Methanol Mixtures
The complexation reactions between methylthymol blue (MTB) and Co2+, Ni2+, Cu2+, Zn2+ and Pb2+ ions have been studied in different water-methanol mixtures at pH 4.45 and 25 °C by a spectrophotometric technique. The stepwise stability constants of the resulting 1:1 and 2:1 (metal ion to ligand) complexes were determined from the absorban...
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ژورنال
عنوان ژورنال: Polyhedron
سال: 2017
ISSN: 0277-5387
DOI: 10.1016/j.poly.2017.03.050